Trimethylaluminum solution 2.0 M in toluene

Stock code :198048
Brand :Sigma-Aldrich
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Trimethylaluminum solution 2.0 M in toluene

Application

Trimethylaluminum solution can be used as a reagent in the synthesis of:
•  Polyhydroxylated cyclohexanes by stereoselective rearrangement of unsaturated glycosides.[3]
•  Partially hydrolyzed trimethylaluminum (PHT) catalyst for the polymerization of olefins.[4]
•  Methyl benzene by methylation of anisole derivatives using nickel-1,3-dicyclohexylimidazol-2-ylidene catalyst system.[5]

Used in a recently reported Al-catalyzed oxidation based on Oppenauer chemistry providing excellent yields of aldehydes and ketones.[2] As a (1:1) complex with binol catalyzes the dynamic kinetic resolution of secondary alcohols with Novozym 435.[1]

Packaging

1 L in Sure/Seal™

The 25 mL Sure/Seal bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

View returnable container options.

4×25, 100, 800 mL in Sure/Seal™

8, 18 L in Kilo-Lab™

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